dimethyldioxirane
Base Information
- Chemical Name: dimethyldioxirane
- CAS No.: 74087-85-7
Reputable manufacturer supply dimethyldioxirane 74087-85-7 in stock with high standard We provide high quality dimethyldioxirane (CAS 74087-85-7), at a very affordable prices to our customers.
1.What is the dimethyldioxirane ?
Dimethyldioxirane (DMDO) is a mild and selective oxidant widely used in organic synthesis for reactions such as oxidative cleavage, epoxidation, and functional group transformations. It efficiently converts cyanoketophosphoranes into α-keto esters and amides under mild conditions and is employed in stereoselective epoxidations, including glucal epoxide formation. DMDO is also useful for generating medium-ring keto-lactones via oxidative cleavage of bicyclic precursors. Its reactivity can be tuned by structural modifications, as seen in the chemoselective oxidation of lactams, where electronic properties influence the preference for N-H or C-H oxidation. The oxidant is valued for its compatibility with sensitive substrates and functional groups, making it a versatile tool in synthetic chemistry.
Dimethyldioxirane acts as a valuable oxidant for the synthesis of polyfunctional aromatic imidazolium monomers bearing epoxides.
2.What is the CAS number for dimethyldioxirane ?
The CAS number of dimethyldioxirane is 74087-85-7.
More information of dimethyldioxirane 74087-85-7 are:
|
CAS?Number |
74087-85-7 |
|
Density |
1.004g/cm3 |
|
Boiling Point |
-21.6±23.0 °C(Predicted) |
|
Vapor Pressure |
3700mmHg at 25°C |
|
Refractive Index |
1.381 |
|
PSA |
25.06000 |
|
LogP |
0.68430 |
3.What is the molecular formula of dimethyldioxirane ?
The chemical formula of?dimethyldioxirane is C3H6 O2 which containing 3 Carbon atoms,6 Hydrogen atoms and 2 Oxygen atoms,and the molecular weight, and the molecular weight of dimethyldioxirane is 74.0794
4.What is dimethyldioxirane(74087-85-7)used for?
Dimethyldioxirane (DMDO) is a mild and selective oxidant widely used in organic synthesis for reactions such as oxidative cleavage, epoxidation, and functional group transformations. It efficiently converts cyanoketophosphoranes into α-keto esters and amides under mild conditions and is employed in stereoselective epoxidations, including glucal epoxide formation. DMDO is also useful for generating medium-ring keto-lactones via oxidative cleavage of bicyclic precursors. Its reactivity can be tuned by structural modifications, as seen in the chemoselective oxidation of lactams, where electronic properties influence the preference for N-H or C-H oxidation. The oxidant is valued for its compatibility with sensitive substrates and functional groups, making it a versatile tool in synthetic chemistry.
InChI:InChI=1/C3H6O2/c1-3(2)4-5-3/h1-2H3
Relevant articles related to dimethyldioxirane:
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Article |
Source |
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Intramolecular epoxide ring opening cyclisation reactions involving guanidines |
Al Shuhaib, Zainab,Arndt, Marcel,Dennis, Mark,Evans, Daniel M.,Jones, Iestyn,Leitmann, Vera,Murphy, Patrick J.,Roberts, Dion,Rowles, Richard,Sadaghiani, Yones K.,Thornhill, Andrew J.,Nash, Robert J.,Hollinshead, Jackie,Bartholomew, Barbara,Tizzard, Graham J.,Coles, Simon J. , p. 1 - 47 (2017) |
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Conversion of Isocyanates to Nitro Compounds with Dimethyldioxirane in Wet Acetone |
Eaton, Philip E.,Wicks, Gene E. , p. 5353 - 5355 (1988) |
5.Reputable manufacturer supply dimethyldioxirane 74087-85-7 in stock with high standard
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