dimethyldioxirane

Base Information

Reputable manufacturer supply dimethyldioxirane 74087-85-7 in stock with high standard We provide high quality dimethyldioxirane (CAS 74087-85-7), at a very affordable prices to our customers.

1.What is the dimethyldioxirane ?

Dimethyldioxirane (DMDO) is a mild and selective oxidant widely used in organic synthesis for reactions such as oxidative cleavage, epoxidation, and functional group transformations. It efficiently converts cyanoketophosphoranes into α-keto esters and amides under mild conditions and is employed in stereoselective epoxidations, including glucal epoxide formation. DMDO is also useful for generating medium-ring keto-lactones via oxidative cleavage of bicyclic precursors. Its reactivity can be tuned by structural modifications, as seen in the chemoselective oxidation of lactams, where electronic properties influence the preference for N-H or C-H oxidation. The oxidant is valued for its compatibility with sensitive substrates and functional groups, making it a versatile tool in synthetic chemistry.

Dimethyldioxirane acts as a valuable oxidant for the synthesis of polyfunctional aromatic imidazolium monomers bearing epoxides.

2.What is the CAS number for dimethyldioxirane ?

The CAS number of dimethyldioxirane is 74087-85-7.

More information of dimethyldioxirane 74087-85-7 are:

CAS?Number

74087-85-7

Density

1.004g/cm3

Boiling Point

-21.6±23.0 °C(Predicted)

Vapor Pressure

3700mmHg at 25°C

Refractive Index

1.381

PSA

25.06000

LogP

0.68430

3.What is the molecular formula of dimethyldioxirane ?

The chemical formula of?dimethyldioxirane is C3H6 O2 which containing 3 Carbon atoms,6 Hydrogen atoms and 2 Oxygen atoms,and the molecular weight, and the molecular weight of dimethyldioxirane is 74.0794

4.What is dimethyldioxirane(74087-85-7)used for?

Dimethyldioxirane (DMDO) is a mild and selective oxidant widely used in organic synthesis for reactions such as oxidative cleavage, epoxidation, and functional group transformations. It efficiently converts cyanoketophosphoranes into α-keto esters and amides under mild conditions and is employed in stereoselective epoxidations, including glucal epoxide formation. DMDO is also useful for generating medium-ring keto-lactones via oxidative cleavage of bicyclic precursors. Its reactivity can be tuned by structural modifications, as seen in the chemoselective oxidation of lactams, where electronic properties influence the preference for N-H or C-H oxidation. The oxidant is valued for its compatibility with sensitive substrates and functional groups, making it a versatile tool in synthetic chemistry.

InChI:InChI=1/C3H6O2/c1-3(2)4-5-3/h1-2H3

Relevant articles related to dimethyldioxirane:

Article

Source

Intramolecular epoxide ring opening cyclisation reactions involving guanidines

Al Shuhaib, Zainab,Arndt, Marcel,Dennis, Mark,Evans, Daniel M.,Jones, Iestyn,Leitmann, Vera,Murphy, Patrick J.,Roberts, Dion,Rowles, Richard,Sadaghiani, Yones K.,Thornhill, Andrew J.,Nash, Robert J.,Hollinshead, Jackie,Bartholomew, Barbara,Tizzard, Graham J.,Coles, Simon J.

, p. 1 - 47 (2017)

Conversion of Isocyanates to Nitro Compounds with Dimethyldioxirane in Wet Acetone

Eaton, Philip E.,Wicks, Gene E.

, p. 5353 - 5355 (1988)

5.Reputable manufacturer supply dimethyldioxirane 74087-85-7 in stock with high standard

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