Mercuric trifluoroacetate
Base Information
- Chemical Name: Mercuric trifluoroacetate
- CAS No.: 13257-51-7
Factory supply Mercuric trifluoroacetate 13257-51-7 with low price
- Molecular Formula: C4F6HgO4
- Molecular Weight: 426.622
- Appearance/Colour: almost white to light beige crystalline powder
- Vapor Pressure: 96.2mmHg at 25°C
- Melting Point: 171-173 °C(lit.)
- Boiling Point: 72.2 °C at 760 mmHg
- PSA： 52.60000
- LogP: 1.10990
Mercuric trifluoroacetate(Cas 13257-51-7) Usage
|
Purification Methods |
Recrystallise it from trifluoroacetic anhydride/trifluoroacetic acid [Lan & Kochi J Am Chem Soc 108 6720 1986]. [Beilstein 2 IV 458.] It is very TOXIC and hygroscopic. |
InChI:InChI=1/C2HF3O2.Hg/c3-2(4,5)1(6)7;/h(H,6,7);
13257-51-7 Relevant articles
-
Haszeldine
, p. 584,587 (1951)
-
-
Barnett,J.R. et al.
, p. 6129 - 6134 (1972)
-
A New Type of Selenium Heterocycle: Tetrachlorobenzo-1,2,3-Triselenole
Humphries, R. E.,Massey, A. G.
, p. 135 - 138 (2007/10/02)
When an excess of selenium is heated wit...
Preparation of O-esters from the corresponding thiol esters: Tert-butyl cyclohexanecarboxylate
Chan, Wan Kit,Masamune,Spessard, Gary O.
, p. 48 - 48 (2017/06/01)
-
13257-51-7 Process route
-
-
mercury(I) trifluoroacetate
-
-
13257-51-7
mercury(II) trifluoroacetate
-
-
104923-33-3
mercury(I) chloride
| Conditions | Yield |
|---|---|
|
With
HCl;
In
trifluoroacetic acid;
|
|
|
With
HCl;
In
trifluoroacetic acid;
|
-
-
76-05-1
trifluoroacetic acid
-
-
12653-71-3
mercury(II) oxide
-
-
13257-51-7
mercury(II) trifluoroacetate
| Conditions | Yield |
|---|---|
|
at 80 ℃;
for 0.5h;
|
100%
|
|
In
neat (no solvent);
HgO and CF3COOH were heated under reflux, CF3COOH was distilled off at 150°C;
|
13257-51-7 Upstream products
-
431-45-8
trifluoroacetyl hypobromite
-
359-47-7
Trifluoracetylhypoiodit
-
76-05-1
trifluoroacetic acid
-
12653-71-3
mercury(II) oxide
13257-51-7 Downstream products
-
35843-80-2
trifluoro-acetic acid pentamethylphenylmethyl ester
-
76-09-5
2,3-dimethyl-2,3-butane diol
-
143859-08-9
O-methyl O-trifluoroacetyl N-phenylphosphoramidate
-
104124-51-8
methyl 2-chloromercurio-3-acetoxy-2,3-diphenylcyclopropane-1-carboxylate